Rings and threads as linkers in metal–organic frameworks and poly-rotaxanes

George F. S. Whitehead; Bryony Cross; Laura Carthy; Victoria A. Milway; Harapriya Rath; Antonio Fernandez; Sarah L. Heath; Christopher A. Muryn; Robin G. Pritchard; Simon J. Teat; Grigore A. Timco; Richard E. P. Winpenny

doi:10.1039/C3CC42300J

Rings and threads as linkers in metal–organic frameworks and poly-rotaxanes†

George F. S. Whitehead,^a Bryony Cross,^a Laura Carthy,^a Victoria A. Milway,^a Harapriya Rath,^a Antonio Fernandez,^a Sarah L. Heath,^a Christopher A. Muryn,^a Robin G. Pritchard,^a Simon J. Teat,^b Grigore A. Timco^a and Richard E. P. Winpenny*^a

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^a The School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, UK
E-mail: richard.winpenny@manchester.ac.uk
Fax: +44 (0)161-275-1001

^b Advanced Light Source, Lawrence Berkeley Laboratory, 1 Cyclotron Road, MS2-400, Berkeley, California 94720, USA

Abstract

Coordination polymers and metal–organic rotaxane frameworks are reported where the organic linker is replaced by functionalised inorganic clusters that act as bridging ligands.

Chemical Communications

Rings and threads as linkers in metal–organic frameworks and poly-rotaxanes†

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Rings and threads as linkers in metal–organic frameworks and poly-rotaxanes

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