Issue 45, 2013
From the journal:

Chemical Communications

Single electron transfer-induced cross-coupling reaction of alkenyl halides with aryl Grignard reagents†

Eiji Shirakawa,*a   Ryo Watabe,a   Takuya Murakamia  and  Tamio Hayashibc  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto, Japan
E-mail: shirakawa@kuchem.kyoto-u.ac.jp

b Institute of Materials Research and Engineering, 3 Research Link, Singapore

c Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore

Abstract

Alkenyl halides were found to undergo coupling with aryl Grignard reagents to give the corresponding styrene derivatives in a stereo-retained manner. The cross-coupling reaction is considered to proceed through a single electron transfer mechanism.

Graphical abstract: Single electron transfer-induced cross-coupling reaction of alkenyl halides with aryl Grignard reagents

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC41923A
Article type
Communication
Submitted
15 Mar 2013
Accepted
15 Apr 2013
First published
16 Apr 2013

Chem. Commun., 2013,49, 5219-5221

Permissions

Request permissions

Single electron transfer-induced cross-coupling reaction of alkenyl halides with aryl Grignard reagents

E. Shirakawa, R. Watabe, T. Murakami and T. Hayashi, Chem. Commun., 2013, 49, 5219 DOI: 10.1039/C3CC41923A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements