Issue 48, 2013
From the journal:

Chemical Communications

Copper-mediated electrophilic imination of alkenylzirconocenes with O-benzoyl ketoximes and aldoximes†

Hailan Liu,ab   Xiaoyu Yan,b   Chao Chen,b   Qingbin Liu*a  and  Chanjuan Xi*b  

* Corresponding authors

a Institute of Chemistry and Chemical Engineering, Hebei Normal University, Shijiazhuang 050091, China

b Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: cjxi@tsinghua.edu.cn

Abstract

Copper-mediated electrophilic imination of alkenylzirconocenes generated in situ from alkynes and zirconocenes is accomplished under mild reaction conditions. The reaction can be used to prepare various 2-azadienes.

Graphical abstract: Copper-mediated electrophilic imination of alkenylzirconocenes with O-benzoyl ketoximes and aldoximes

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Article information

DOI
https://doi.org/10.1039/C3CC41574K
Article type
Communication
Submitted
01 Mar 2013
Accepted
25 Apr 2013
First published
25 Apr 2013

Chem. Commun., 2013,49, 5513-5515

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Copper-mediated electrophilic imination of alkenylzirconocenes with O-benzoyl ketoximes and aldoximes

H. Liu, X. Yan, C. Chen, Q. Liu and C. Xi, Chem. Commun., 2013, 49, 5513 DOI: 10.1039/C3CC41574K

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