Issue 45, 2013
From the journal:

Chemical Communications

Pt, Pd and Au nanoparticles supported on a DNA–MMT hybrid: efficient catalysts for highly selective oxidation of primary alcohols to aldehydes, acids and esters†

Lin Tang,a   Xuefeng Guo,a   Yunfeng Li,a   Shuai Zhang,a   Zhenggen Zhaa  and  Zhiyong Wang*a  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, P. R. China
E-mail: zwang3@ustc.edu.cn
Fax: +86 551-360-3185

Abstract

Novel DNA–MMT hybrid supported metal nanoparticle catalysts, such as Pt/DNA–MMT, Pd/DNA–MMT, Au/DNA–MMT, were prepared for application in highly selective aerobic oxidation of primary alcohols to aldehydes, acids and esters, respectively. Taking advantage of the water-soluble reversibility of these catalysts, all the transformations could be performed smoothly in water and reuse of the catalysts has also been accomplished by a very simple phase separation process.

Graphical abstract: Pt, Pd and Au nanoparticles supported on a DNA–MMT hybrid: efficient catalysts for highly selective oxidation of primary alcohols to aldehydes, acids and esters

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Article information

DOI
https://doi.org/10.1039/C3CC41545G
Article type
Communication
Submitted
28 Feb 2013
Accepted
11 Apr 2013
First published
11 Apr 2013

Chem. Commun., 2013,49, 5213-5215

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Pt, Pd and Au nanoparticles supported on a DNA–MMT hybrid: efficient catalysts for highly selective oxidation of primary alcohols to aldehydes, acids and esters

L. Tang, X. Guo, Y. Li, S. Zhang, Z. Zha and Z. Wang, Chem. Commun., 2013, 49, 5213 DOI: 10.1039/C3CC41545G

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