Issue 33, 2013
From the journal:

Chemical Communications

Unprecedented 1,3-migration of the arylligand in metallacyclic aryl α-naphthyl Pt(iv) difluorides to produce β-arylnaphthyl Pt(ii) complexes†

Ina S. Dubinsky-Davidchik,a   Israel Goldberg,a   Arkadi Vigalok*a  and  Andrei N. Vedernikov*b  

* Corresponding authors

a School of Chemistry, The Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel
E-mail: avigal@post.tau.ac.il
Fax: +972-3-6406205
Tel: +972-3-6408617

b Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA
E-mail: avederni@umd.edu
Fax: +1-301-314-9121
Tel: +1-301-405-2784

Abstract

Electrophilic fluorination of aryl α-naphthyl Pt(II) complexes leads to an unprecedented 1,3-migration of the aryl ligand to the β-position of the naphthyl group. The reaction proceeds via the initial oxidative addition of two fluoro ligands to the Pt center followed by C(sp2)–C(sp2) coupling and aryl migration.

Graphical abstract: Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl α-naphthyl Pt(iv) difluorides to produce β-arylnaphthyl Pt(ii) complexes

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DOI
https://doi.org/10.1039/C3CC41079J
Article type
Communication
Submitted
07 Feb 2013
Accepted
08 Mar 2013
First published
08 Mar 2013

Chem. Commun., 2013,49, 3446-3448

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Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl α-naphthyl Pt(IV) difluorides to produce β-arylnaphthyl Pt(II) complexes

I. S. Dubinsky-Davidchik, I. Goldberg, A. Vigalok and A. N. Vedernikov, Chem. Commun., 2013, 49, 3446 DOI: 10.1039/C3CC41079J

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