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Issue 22, 2013
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Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

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Abstract

The reaction of acetylene ethers with difluorocarbene (CF2), generated from the Ruppert–Prakash reagent, unexpectedly gave rise to co-produced fluorinated bicyclic [2.1.1]-hex-2-ene and cyclohepta-1,4-diene ring products.

Graphical abstract: Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

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Article information


Submitted
19 Dec 2012
Accepted
25 Jan 2013
First published
28 Jan 2013

Chem. Commun., 2013,49, 2189-2191
Article type
Communication

Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

P. W. Chia, D. Bello, A. M. Z. Slawin and D. O'Hagan, Chem. Commun., 2013, 49, 2189
DOI: 10.1039/C3CC39066G

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