Coordinative trapping of the boron β-diketiminato system [B(NMesCMe)2CH] via metal-templated synthesis

Erkan Firinci; Joshua I. Bates; Ian M. Riddlestone; Nicholas Phillips; Simon Aldridge

doi:10.1039/C3CC38073D

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Coordinative trapping of the boron β-diketiminato system [B(NMesCMe)₂CH] via metal-templated synthesis†

Erkan Firinci,‡^a Joshua I. Bates,^a Ian M. Riddlestone,^a Nicholas Phillips^a and Simon Aldridge*^a

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* Corresponding authors

^a Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Rd, Oxford, UK
E-mail: Simon.Aldridge@chem.ox.ac.uk
Tel: +44 (0)1865 285201

Abstract

A metal templated synthetic approach gives access to [Cp*Fe(CO)₂{B(NMesCMe)₂CH}][BAr^f₄], and represents the first example of coordinative trapping of the elusive [B(NRCMe)₂CH] fragment.

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Article information

DOI: https://doi.org/10.1039/C3CC38073D
Article type: Communication
Submitted: 08 Nov 2012
Accepted: 08 Jan 2013
First published: 10 Jan 2013

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Chem. Commun., 2013,49, 1509-1511

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Coordinative trapping of the boron β-diketiminato system [B(NMesCMe)₂CH] via metal-templated synthesis

E. Firinci, J. I. Bates, I. M. Riddlestone, N. Phillips and S. Aldridge, Chem. Commun., 2013, 49, 1509 DOI: 10.1039/C3CC38073D

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