Issue 51, 2013
From the journal:

Chemical Communications

An ultra-low Pd loading nanocatalyst with high activity and stability for CO oxidative coupling to dimethyl oxalate†

Si-Yan Peng,ab   Zhong-Ning Xu,ab   Qing-Song Chen,ab   Yu-Min Chen,ab   Jing Sun,a   Zhi-Qiao Wang,ab   Ming-Sheng Wanga  and  Guo-Cong Guo*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: gcguo@fjirsm.ac.cn
Fax: +86-591-83714946
Tel: +86-591-83705882

b Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China

Abstract

A Pd/α-Al2O3 nanocatalyst with ultra-low Pd loading exhibits high activity and stability for CO oxidative coupling to dimethyl oxalate, which was prepared by a Cu2+-assisted in situ reduction method at room temperature. The small size and high dispersion of Pd nanoparticles facilitated by Cu2+ ions are responsible for the excellent catalytic activity.

Graphical abstract: An ultra-low Pd loading nanocatalyst with high activity and stability for CO oxidative coupling to dimethyl oxalate

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Article information

DOI
https://doi.org/10.1039/C3CC00219E
Article type
Communication
Submitted
10 Jan 2013
Accepted
22 Mar 2013
First published
22 Mar 2013

Chem. Commun., 2013,49, 5718-5720

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An ultra-low Pd loading nanocatalyst with high activity and stability for CO oxidative coupling to dimethyl oxalate

S. Peng, Z. Xu, Q. Chen, Y. Chen, J. Sun, Z. Wang, M. Wang and G. Guo, Chem. Commun., 2013, 49, 5718 DOI: 10.1039/C3CC00219E

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