Issue 23, 2013
From the journal:

Chemical Communications

Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(ii) metal–organic framework†

Euna Jeong,a   Woo Ram Lee,a   Dae Won Ryu,a   Yeonga Kim,a   Won Ju Phang,a   Eui Kwan Kohb  and  Chang Seop Hong*a  

* Corresponding authors

a Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea
E-mail: cshong@korea.ac.kr

b Nano-Bio System Research Team, Korea Basic Science Institute, Seoul 136-713, Korea

Abstract

An aqua-bridged Mn metal–organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange–resolvation and desolvation–resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO2 uptake over N2, H2, and CH4. Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units.

Graphical abstract: Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(ii) metal–organic framework

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC00093A
Article type
Communication
Submitted
05 Jan 2013
Accepted
01 Feb 2013
First published
04 Feb 2013

Chem. Commun., 2013,49, 2329-2331

Permissions

Request permissions

Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(II) metal–organic framework

E. Jeong, W. R. Lee, D. W. Ryu, Y. Kim, W. J. Phang, E. K. Koh and C. S. Hong, Chem. Commun., 2013, 49, 2329 DOI: 10.1039/C3CC00093A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements