Issue 29, 2013
From the journal:

Chemical Communications

Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols†

Kelly A. Volpa  and  Andrew M. Harned*a  

* Corresponding authors

a Department of Chemistry, University of Minnesota, 207 Pleasant St SE, Minneapolis, MN, USA
E-mail: harned@umn.edu
Fax: +1 612-626-7541
Tel: +1 612-625-1036

Abstract

Molecular modelling of an iodine(III) phenoxide was used as a starting point in the design of chiral aryl iodide catalysts for stereoselective oxidative dearomatization reactions. Using this approach, catalysts derived from 8-iodotetralone and tartaric acid were constructed and used to synthesize enantioenriched para-quinols from phenols.

Graphical abstract: Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

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Article information

DOI
https://doi.org/10.1039/C3CC00013C
Article type
Communication
Submitted
01 Jan 2013
Accepted
25 Feb 2013
First published
26 Feb 2013

Chem. Commun., 2013,49, 3001-3003

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Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

K. A. Volp and A. M. Harned, Chem. Commun., 2013, 49, 3001 DOI: 10.1039/C3CC00013C

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