Issue 38, 2013

Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

Abstract

Infinite square-tubular helices, [CuCl2(L)(S)] (L = bis(4-pyridyl)methylvinylsilane; S = Me2SO, HCONMe2), were constructed. This helical system affords three kinds of P, M crystals in Me2SO, and racemic crystals in HCONMe2. The cyclic voltammogram (CV) technique using the M-crystals is an effective tool for discerning the chirality of proline.

Graphical abstract: Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

Supplementary files

Article information

Article type
Communication
Submitted
01 Jan 2013
Accepted
25 Mar 2013
First published
25 Mar 2013

Chem. Commun., 2013,49, 4000-4002

Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

K. H. Park, T. H. Noh, Y. Shim and O. Jung, Chem. Commun., 2013, 49, 4000 DOI: 10.1039/C3CC00005B

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