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Issue 16, 2013
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Catalytic intermolecular carbon electrophile induced semipinacol rearrangement

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Abstract

A catalytic intermolecular carbon electrophile induced semipinacol rearrangement was realized and the asymmetric version was also preliminarily accomplished with 92% and 82% ee. The complex tricyclic system architecture with four continuous stereogenic centers could be achieved from simple starting materials in a single step under mild conditions.

Graphical abstract: Catalytic intermolecular carbon electrophile induced semipinacol rearrangement

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Supplementary files

Article information


Submitted
29 Nov 2012
Accepted
07 Jan 2013
First published
08 Jan 2013

Chem. Commun., 2013,49, 1648-1650
Article type
Communication

Catalytic intermolecular carbon electrophile induced semipinacol rearrangement

Q. Zhang, X. Zhang, B. Li, K. Xiang, F. Zhang, S. Wang and Y. Tu, Chem. Commun., 2013, 49, 1648
DOI: 10.1039/C2CC38585F

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