Issue 10, 2013
From the journal:

Chemical Communications

Dual emissive borane–BODIPY dyads: molecular conformation control over electronic properties and fluorescence response towards fluoride ions†

Chinna Ayya Swamy P,a   Sanjoy Mukherjeea  and  Pakkirisamy Thilagar*a  

* Corresponding authors

a Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India
E-mail: thilagar@ipc.iisc.ernet.in
Fax: 0091-80-23601552
Tel: 0091-80-22933353

Abstract

Facile synthesis of two new dimesitylboryl appended BODIPYs is reported. The two dyads have similar fluorescent chromophores but differ in their molecular conformations. They exhibit dual fluorescence, intramolecular energy transfer between boryl and BODIPY chromophores and different fluorescence responses (emission enhancement and quenching) upon fluoride binding.

Graphical abstract: Dual emissive borane–BODIPY dyads: molecular conformation control over electronic properties and fluorescence response towards fluoride ions

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Article information

DOI
https://doi.org/10.1039/C2CC38352G
Article type
Communication
Submitted
14 Sep 2012
Accepted
07 Dec 2012
First published
10 Dec 2012

Chem. Commun., 2013,49, 993-995

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Dual emissive borane–BODIPY dyads: molecular conformation control over electronic properties and fluorescence response towards fluoride ions

C. A. Swamy P, S. Mukherjee and P. Thilagar, Chem. Commun., 2013, 49, 993 DOI: 10.1039/C2CC38352G

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