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Issue 10, 2013
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Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

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Abstract

[Pd(NHC)(PR3)] complexes were shown to be active catalysts in the dehydrogenation of ammonia borane and the subsequent hydrogenation of unsaturated compounds at very low catalyst loadings (0.05 mol% for some substrates).

Graphical abstract: Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

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Publication details

The article was received on 11 Nov 2012, accepted on 12 Dec 2012 and first published on 14 Dec 2012


Article type: Communication
DOI: 10.1039/C2CC38145A
Citation: Chem. Commun., 2013,49, 1005-1007

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    Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

    C. E. Hartmann, V. Jurčík, O. Songis and C. S. J. Cazin, Chem. Commun., 2013, 49, 1005
    DOI: 10.1039/C2CC38145A

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