Issue 5, 2013
From the journal:

Chemical Communications

Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine)†

Saul H. Lapidus,a   Jamie L. Manson,b   Hyunsoo Park,a   Alexander J. Clement,a   Saman Ghannadzadeh,c   Paul Goddard,c   Tom Lancaster,d   Johannes S. Möller,c   Stephen J. Blundell,c   Mark T. F. Telling,ef   Jinhee Kang,g   Myung-Hwan Whangbog  and  John A. Schlueter*a  

* Corresponding authors

a Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA
E-mail: JASchlueter@anl.gov
Fax: +1-630-252-9555
Tel: +1-630-252-3588

b Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA

c University of Oxford, Department of Physics, Clarendon Laboratory, Parks Road, Oxford OX1 3PU, UK

d Centre for Materials Physics, Durham University, South Road, Durham, UK

e ISIS Facility, Rutherford Appleton Laboratory, Chilton, Oxfordshire, UK

f Department of Materials, University of Oxford, Parks Road, Oxford, UK

g Department of Chemistry, North Carolina State University, Raleigh, NC 27695, USA

Abstract

CuF2(H2O)2(3-chloropyridine) possesses a five-coordinate Cu2+ center with a slightly distorted trigonal bypyramidal coordination geometry. Strong intermolecular F⋯H–O hydrogen bonds enable the formation of 2D layers and provide the primary magnetic exchange path that leads to the stabilization of long-range antiferromagnetic (AFM) order below TN = 2.1 K.

Graphical abstract: Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine)

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Article information

DOI
https://doi.org/10.1039/C2CC37444G
Article type
Communication
Submitted
12 Oct 2012
Accepted
18 Nov 2012
First published
20 Nov 2012

Chem. Commun., 2013,49, 499-501

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Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine)

S. H. Lapidus, J. L. Manson, H. Park, A. J. Clement, S. Ghannadzadeh, P. Goddard, T. Lancaster, J. S. Möller, S. J. Blundell, M. T. F. Telling, J. Kang, M. Whangbo and J. A. Schlueter, Chem. Commun., 2013, 49, 499 DOI: 10.1039/C2CC37444G

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