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Issue 39, 2013
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Rhodium-catalyzed cysteine modification with diazo reagents

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Abstract

A simple rhodium(II) complex catalyzes cysteine modification with diazo reagents. The reaction is marked by clean cysteine selectivity and mild reaction conditions. The resulting linkage is significantly more stable in human plasma serum, when compared to common maleimide reagents.

Graphical abstract: Rhodium-catalyzed cysteine modification with diazo reagents

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Supplementary files

Article information


Submitted
08 Oct 2012
Accepted
12 Nov 2012
First published
13 Nov 2012

Chem. Commun., 2013,49, 4166-4168
Article type
Communication

Rhodium-catalyzed cysteine modification with diazo reagents

R. Kundu and Z. T. Ball, Chem. Commun., 2013, 49, 4166
DOI: 10.1039/C2CC37323H

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