Issue 2, 2013
From the journal:

Chemical Communications

Investigation of size-dependent properties of sub-nanometer palladium clusters encapsulated within a polyamine dendrimer†

Takayuki Kibata,a   Takato Mitsudome,a   Tomoo Mizugaki,a   Koichiro Jitsukawaa  and  Kiyotomi Kaneda*ab  

* Corresponding authors

a Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
E-mail: kaneda@cheng.es.osaka-u.ac.jp
Fax: +81 6-6850-6260
Tel: +81 6-6850-6260

b Research Center for Solar Energy Chemistry, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan

Abstract

This study describes the first example of the investigation of electronic, geometric, and catalytic properties of Pd subnano metal clusters of Pd4, Pd8, and Pd16 stabilized by poly(propylene imine) (PPI) dendrimers using XAFS and IR analyses. The relations among these properties are also discussed.

Graphical abstract: Investigation of size-dependent properties of sub-nanometer palladium clusters encapsulated within a polyamine dendrimer

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Article information

DOI
https://doi.org/10.1039/C2CC37038G
Article type
Communication
Submitted
28 Sep 2012
Accepted
09 Nov 2012
First published
12 Nov 2012

Chem. Commun., 2013,49, 167-169

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Investigation of size-dependent properties of sub-nanometer palladium clusters encapsulated within a polyamine dendrimer

T. Kibata, T. Mitsudome, T. Mizugaki, K. Jitsukawa and K. Kaneda, Chem. Commun., 2013, 49, 167 DOI: 10.1039/C2CC37038G

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