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Issue 39, 2013
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[Cu30I16(mtpmt)1210-S4)]: an unusual 30-membered copper(I) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis

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Abstract

The Cu(I)-mediated C–S bond cleavage of 5-methyl-4-(p-tolyl)pyrimidine-2-thiol (mtpmtH) gave one 30-nuclear cluster [Cu30I16(mtpmt)1210-S4)], one polymeric complex [(bmtpms)Cu-(μ-I)]n and one tetranuclear complex [(bmptmds){Cu(μ-I)}2]2; the 30-nuclear cluster displayed excellent catalytic performances in the coupling reactions of N-heterocycles and arylboronic acids and could be recycled and reused.

Graphical abstract: [Cu30I16(mtpmt)12(μ10-S4)]: an unusual 30-membered copper(i) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis

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Publication details

The article was received on 12 Aug 2012, accepted on 11 Oct 2012 and first published on 19 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC36736J
Chem. Commun., 2013,49, 4259-4261

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    [Cu30I16(mtpmt)1210-S4)]: an unusual 30-membered copper(I) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis

    H. Li, W. Zhao, H. Li, Z. Xu, W. Wang and J. Lang, Chem. Commun., 2013, 49, 4259
    DOI: 10.1039/C2CC36736J

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