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Issue 1, 2013
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Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core

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Abstract

Three heterometallic cluster complexes {Ln12Mo4} featuring an Ln12 core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42− anions as ancillary ligands. Magnetic studies of the {Gd12Mo4} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(III) ions.

Graphical abstract: Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core

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Article information


Submitted
07 Sep 2012
Accepted
16 Oct 2012
First published
16 Oct 2012

Chem. Commun., 2013,49, 36-38
Article type
Communication

Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core

Y. Zheng, Q. Zhang, L. Long, R. Huang, A. Müller, J. Schnack, L. Zheng and Z. Zheng, Chem. Commun., 2013, 49, 36
DOI: 10.1039/C2CC36530H

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