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Issue 39, 2013
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Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(ii), Se(ii) and Te(ii) mono- and dications

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Abstract

The syntheses and structural characterization of carbene-stabilized chalcogen centred mono- and dications employing a reverse electron demand onio-substitutent transfer strategy are reported. The electronic structures of these compounds were determined by density functional calculations and their reactivity towards Pd(0) centres was evaluated.

Graphical abstract: Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(ii), Se(ii) and Te(ii) mono- and dications

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Submitted
27 Aug 2012
Accepted
12 Oct 2012
First published
29 Oct 2012

Chem. Commun., 2013,49, 4145-4147
Article type
Communication

Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(II), Se(II) and Te(II) mono- and dications

Á. Kozma, J. Petuškova, C. W. Lehmann and M. Alcarazo, Chem. Commun., 2013, 49, 4145
DOI: 10.1039/C2CC36225B

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