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Issue 99, 2012
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Synthesis and post-synthetic modification of MIL-101(Cr)-NH2via a tandem diazotisation process

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Abstract

The functionalised metal–organic framework MIL-101(Cr)-NH2, containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo- and azo dye-functional groups into the pores.

Graphical abstract: Synthesis and post-synthetic modification of MIL-101(Cr)-NH2via a tandem diazotisation process

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Supplementary files

Article information


Submitted
31 Aug 2012
Accepted
30 Sep 2012
First published
18 Oct 2012

Chem. Commun., 2012,48, 12053-12055
Article type
Communication

Synthesis and post-synthetic modification of MIL-101(Cr)-NH2via a tandem diazotisation process

D. Jiang, L. L. Keenan, A. D. Burrows and K. J. Edler, Chem. Commun., 2012, 48, 12053 DOI: 10.1039/C2CC36344E

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