Jump to main content
Jump to site search

Issue 91, 2012
Previous Article Next Article

Electron-transfer properties of a nonheme manganese(iv)–oxo complex acting as a stronger one-electron oxidant than the iron(iv)–oxo analogue

Author affiliations

Abstract

Electron-transfer properties of a nonheme Mn(IV)–oxo complex, [(Bn-TPEN)MnIV(O)]2+, reveals that Mn(IV)–oxo complex acts as a stronger one-electron oxidant than the Fe(IV)–oxo analogue. As a result, an electron transfer process in N-dealkylation has been detected by a transient radical cation intermediate, para-Me-DMA˙+, in the oxidation of para-Me-DMA by [(Bn-TPEN)MnIV(O)]2+.

Graphical abstract: Electron-transfer properties of a nonheme manganese(iv)–oxo complex acting as a stronger one-electron oxidant than the iron(iv)–oxo analogue

Back to tab navigation

Supplementary files

Article information


Submitted
30 Aug 2012
Accepted
19 Sep 2012
First published
21 Sep 2012

Chem. Commun., 2012,48, 11187-11189
Article type
Communication

Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue

H. Yoon, Y. Morimoto, Y. Lee, W. Nam and S. Fukuzumi, Chem. Commun., 2012, 48, 11187
DOI: 10.1039/C2CC36291K

Social activity

Search articles by author

Spotlight

Advertisements