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Issue 86, 2012

A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water

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Abstract

The synthesis and characterisation of a three-dimensional lithium–organic framework MIL-145 is described, which upon thermal treatment yields a second open framework, MIL-146, that contains four and three-coordinate lithium centres: the coordinatively unsaturated trigonal planar lithium centres are able to reversibly bind water with crystallinity maintained, while the dehydrated phase shows preferential adsorption of CO2 over N2.

Graphical abstract: A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water

Supplementary files

Article information


Submitted
13 Aug 2012
Accepted
31 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10639-10641
Article type
Communication

A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water

R. E. Osta, M. Frigoli, J. Marrot, N. Guillou, H. Chevreau, R. I. Walton and F. Millange, Chem. Commun., 2012, 48, 10639 DOI: 10.1039/C2CC35861A

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