Issue 84, 2012
From the journal:

Chemical Communications

Deciphering DNA-based asymmetric catalysis through intramolecular Friedel–Crafts alkylations†

Soyoung Park,a   Keiichi Ikehata,a   Ryo Watabe,a   Yuta Hidaka,a   Arivazhagan Rajendrana  and  Hiroshi Sugiyama*abc  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Japan

b Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida-ushinomiyacho, Sakyo-ku, Japan

c CREST, Japan Science and Technology Corporation (JST), Sanbancho, Chiyoda-ku, Japan
E-mail: hs@kuchem.kyoto-u.ac.jp
Fax: +81-75-753-3670
Tel: +81-75-753-4002

Abstract

We describe asymmetric intramolecular Friedel–Crafts alkylations with a DNA-based hybrid catalyst and propose a plausible binding model. This study shows promise for studying relationships between the helical chirality of DNA and enantioselectivity of the chemical reaction.

Graphical abstract: Deciphering DNA-based asymmetric catalysis through intramolecular Friedel–Crafts alkylations

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Article information

DOI
https://doi.org/10.1039/C2CC35625B
Article type
Communication
Submitted
17 May 2012
Accepted
03 Sep 2012
First published
03 Sep 2012

Chem. Commun., 2012,48, 10398-10400

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Deciphering DNA-based asymmetric catalysis through intramolecular Friedel–Crafts alkylations

S. Park, K. Ikehata, R. Watabe, Y. Hidaka, A. Rajendran and H. Sugiyama, Chem. Commun., 2012, 48, 10398 DOI: 10.1039/C2CC35625B

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