Issue 77, 2012

A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

Abstract

Carbazole-containing porphyrinoid 3 was synthesised for the first time via Suzuki–Miyaura cross-coupling reaction. Oxidation with MnO2 yielded its porphyrin-state 2 featuring macrocyclic aromaticity in exchange for the loss of the resonance energies of the benzene rings.

Graphical abstract: A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

Supplementary files

Article information

Article type
Communication
Submitted
31 Jul 2012
Accepted
09 Aug 2012
First published
09 Aug 2012

Chem. Commun., 2012,48, 9640-9642

A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

L. Arnold, M. Baumgarten and K. Müllen, Chem. Commun., 2012, 48, 9640 DOI: 10.1039/C2CC35550G

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