Issue 83, 2012

Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

Abstract

A chromiumtricarbonyl-bound iridacycle displays novel catalytic virtues for the conversion of terminal aromatic alkynes into racemic N-phenyl, 1-arylethylamines by tandem hydro-amination and hydrosilation/protodesilation reactions under mild “one pot” conditions.

Graphical abstract: Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

Supplementary files

Article information

Article type
Communication
Submitted
30 Jul 2012
Accepted
30 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10310-10312

Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

W. Iali, F. L. Paglia, X. L. Goff, D. Sredojević, M. Pfeffer and J. Djukic, Chem. Commun., 2012, 48, 10310 DOI: 10.1039/C2CC35520E

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