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Issue 84, 2012
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A silver complex with an N,S,S-macrocyclic ligand bearing an anthracene pendant arm for optical ethylene monitoring

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Abstract

We have synthesised a silver(I) complex with a metal–arene interaction, where the anthracene ring of the ligand sidearm is positioned above the silver(I) ion. The interaction is disrupted by ethylene coordination to the silver(I). The reversible interconversion between the metal–arene and metal–ethylene interactions allowed us to monitor the presence of ethylene.

Graphical abstract: A silver complex with an N,S,S-macrocyclic ligand bearing an anthracene pendant arm for optical ethylene monitoring

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Article information


Submitted
21 Jul 2012
Accepted
06 Sep 2012
First published
06 Sep 2012

Chem. Commun., 2012,48, 10392-10394
Article type
Communication

A silver complex with an N,S,S-macrocyclic ligand bearing an anthracene pendant arm for optical ethylene monitoring

Y. Hitomi, T. Nagai and M. Kodera, Chem. Commun., 2012, 48, 10392
DOI: 10.1039/C2CC35277J

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