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Issue 86, 2012
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Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(ii)

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Abstract

A tripyridyl multi-interactive ligand TPHAP is prepared by a one-pot reaction on a gram scale. Network formation of Co(II) with TPHAP gave kinetic and thermally more stable products. The kinetic network showed an unprecedented dynamic network transformation on the crystal surface by a ligand exchange reaction.

Graphical abstract: Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(ii)

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Supplementary files

Article information


Submitted
16 Jul 2012
Accepted
11 Sep 2012
First published
12 Sep 2012

Chem. Commun., 2012,48, 10651-10653
Article type
Communication

Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(II)

Y. Yakiyama, A. Ueda, Y. Morita and M. Kawano, Chem. Commun., 2012, 48, 10651
DOI: 10.1039/C2CC35078E

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