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Issue 84, 2012
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Photoswitching of the second-order nonlinearity of a tetrahedral octupolar multi DTE-based copper(i) complex

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Abstract

The modulation of the quadratic NLO response of an octupolar metal-based chromophore featuring four photochromic dithienylethene units is reported. Quantum mechanical simulations are consistent with a full switching of the DTE units and reproduce the strong enhancement of the NLO response.

Graphical abstract: Photoswitching of the second-order nonlinearity of a tetrahedral octupolar multi DTE-based copper(i) complex

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Article information


Submitted
12 Jul 2012
Accepted
31 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10395-10397
Article type
Communication

Photoswitching of the second-order nonlinearity of a tetrahedral octupolar multi DTE-based copper(I) complex

H. Nitadori, L. Ordronneau, J. Boixel, D. Jacquemin, A. Boucekkine, A. Singh, M. Akita, I. Ledoux, V. Guerchais and H. L. Bozec, Chem. Commun., 2012, 48, 10395
DOI: 10.1039/C2CC34999J

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