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Issue 75, 2012
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Functional group effects on metal–organic framework topology

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Abstract

Functionalization of the ligand 1,3,5-tris(4-carboxyphenyl)benzene (H3BTB) has been realized with methoxy (H3BTB–[OMe]3) and hydroxy (H3BTB–[OH]3) groups. Combining H3BTB–[OMe]3 and Zn(II) results in the formation of the first isostructural, functionalized analogue of MOF-177 (MOF-177–OMe), while the combination of H3BTB–[OH]3 and Zn(II) generates a rare, interpenetrated pcu-e framework.

Graphical abstract: Functional group effects on metal–organic framework topology

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Article information


Submitted
11 Jul 2012
Accepted
07 Aug 2012
First published
08 Aug 2012

Chem. Commun., 2012,48, 9370-9372
Article type
Communication

Functional group effects on metal–organic framework topology

P. V. Dau, K. K. Tanabe and S. M. Cohen, Chem. Commun., 2012, 48, 9370
DOI: 10.1039/C2CC34938H

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