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Issue 69, 2012
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Phosphine-catalyzed asymmetric [4+1] annulation of Morita–Baylis–Hillman carbonates with dicyano-2-methylenebut-3-enoates

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Abstract

A novel asymmetric [4+1] annulation of MBH carbonates with dicyano-2-methylenebut-3-enoates has been developed for the first time, providing an efficient and enantioselective synthesis of highly functionalized cyclopentenes bearing one all-carbon quaternary stereogenic center.

Graphical abstract: Phosphine-catalyzed asymmetric [4+1] annulation of Morita–Baylis–Hillman carbonates with dicyano-2-methylenebut-3-enoates

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Publication details

The article was received on 28 Jun 2012, accepted on 12 Jul 2012 and first published on 12 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC34619B
Chem. Commun., 2012,48, 8664-8666

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    Phosphine-catalyzed asymmetric [4+1] annulation of Morita–Baylis–Hillman carbonates with dicyano-2-methylenebut-3-enoates

    X. Zhang, H. Deng, L. Huang, Y. Wei and M. Shi, Chem. Commun., 2012, 48, 8664
    DOI: 10.1039/C2CC34619B

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