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Issue 94, 2012
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New zeolite Al-COE-4: reaching highly shape-selective catalytic performance through interlayer expansion

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Abstract

A ferrierite-type layered aluminosilicate, Al-RUB-36, was prepared for the first time and its interlayer expansion resulted in new zeolite catalysts denoted Al-COE-3 and Al-COE-4. Decane hydroconversion tests demonstrated the highly active and shape-selective nature of the new Al-COE-4 catalyst with an unprecedented isomerization yield, highlighting the potential of this material as a hydroisomerization catalyst. This is the first report on achieving shape-selectivity via interlayer expansion.

Graphical abstract: New zeolite Al-COE-4: reaching highly shape-selective catalytic performance through interlayer expansion

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Article information


Submitted
20 Jun 2012
Accepted
10 Oct 2012
First published
11 Oct 2012

Chem. Commun., 2012,48, 11549-11551
Article type
Communication

New zeolite Al-COE-4: reaching highly shape-selective catalytic performance through interlayer expansion

B. Yilmaz, U. Müller, M. Feyen, H. Zhang, F. Xiao, T. De Baerdemaeker, B. Tijsebaert, P. Jacobs, D. De Vos, W. Zhang, X. Bao, H. Imai, T. Tatsumi and H. Gies, Chem. Commun., 2012, 48, 11549
DOI: 10.1039/C2CC34433E

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