Issue 71, 2012
From the journal:

Chemical Communications

Paramagnetic aluminium β-diketiminate†

Jani Moilanen,a   Javier Borau-Garcia,b   Roland Roeslerb  and  Heikki M. Tuononen*a  

* Corresponding authors

a Department of Chemistry, University of Jyväskylä, P.O. Box 35, Jyväskylä, Finland
E-mail: heikki.m.tuononen@jyu.fi
Fax: +358-14-260-2501
Tel: +358-45-235-8588

b Department of Chemistry, University of Calgary, 2500 University Drive N.W., Calgary, AB, Canada

Abstract

The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic complex was characterized by EPR spectroscopy and computational chemistry.

Graphical abstract: Paramagnetic aluminium β-diketiminate

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Article information

DOI
https://doi.org/10.1039/C2CC34051H
Article type
Communication
Submitted
06 Jun 2012
Accepted
18 Jul 2012
First published
18 Jul 2012

Chem. Commun., 2012,48, 8949-8951

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Paramagnetic aluminium β-diketiminate

J. Moilanen, J. Borau-Garcia, R. Roesler and H. M. Tuononen, Chem. Commun., 2012, 48, 8949 DOI: 10.1039/C2CC34051H

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