Ph2PI as a reduction/phosphination reagent: providing easy access to phosphine oxides

Feijun Wang; Mingliang Qu; Feng Chen; Qin Xu; Min Shi

doi:10.1039/C2CC33908K

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Ph₂PI as a reduction/phosphination reagent: providing easy access to phosphine oxides†

Feijun Wang,*^a Mingliang Qu,^a Feng Chen,^a Qin Xu*^a and Min Shi*^ab

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* Corresponding authors

^a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, and 130 MeiLong Road, Shanghai 200237, P. R. China
E-mail: feijunwang@ecust.edu.cn, qinxu@ecust.edu.cn

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. China
E-mail: mshi@mail.sioc.ac.cn

Abstract

The reaction of aldehydes with Ph₂PI provides a facile way to the synthesis of pentavalent phosphine compounds with moderate to good yields.

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Article information

DOI: https://doi.org/10.1039/C2CC33908K
Article type: Communication
Submitted: 31 May 2012
Accepted: 04 Jul 2012
First published: 05 Jul 2012

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Chem. Commun., 2012,48, 8580-8582

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Ph₂PI as a reduction/phosphination reagent: providing easy access to phosphine oxides

F. Wang, M. Qu, F. Chen, Q. Xu and M. Shi, Chem. Commun., 2012, 48, 8580 DOI: 10.1039/C2CC33908K

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