Issue 67, 2012
From the journal:

Chemical Communications

Dual templated synthesis of silver acetylide cluster-encapsulated supramolecular boxes†

Cai-Yan Gao,a   Xin He,a   Liang Zhao*a  and  Mei-Xiang Wang*a  

* Corresponding authors

a The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: zhaolchem@mail.tsinghua.edu.cn, wangmx@mail.tsinghua.edu.cn

Abstract

A dual-templated approach for the controllable synthesis of metal cluster complexes is described. By using an acetylide-containing anion with specific geometry as a central template and a macrocyclic coordinative compound as a peripheral one, two multinuclear silver-acetylide cluster-encapsulated supramolecular boxes were synthesized.

Graphical abstract: Dual templated synthesis of silver acetylide cluster-encapsulated supramolecular boxes

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Article information

DOI
https://doi.org/10.1039/C2CC33757F
Article type
Communication
Submitted
25 May 2012
Accepted
02 Jul 2012
First published
03 Jul 2012

Chem. Commun., 2012,48, 8368-8370

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Dual templated synthesis of silver acetylide cluster-encapsulated supramolecular boxes

C. Gao, X. He, L. Zhao and M. Wang, Chem. Commun., 2012, 48, 8368 DOI: 10.1039/C2CC33757F

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