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Issue 62, 2012
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Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(III) complexes with 2,3-quinoxalinediolate ligands

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Abstract

The coordination chemistry of the 2,3-quinoxalinediolate ligand with different lanthanide(III) ions in basic media in air affords a new family of carbonato-bridged M2III compounds (M = Pr, Gd and Dy), the Dy2III analogue exhibiting slow magnetic relaxation behaviour typical of single-molecule magnets.

Graphical abstract: Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(iii) complexes with 2,3-quinoxalinediolate ligands

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Publication details

The article was received on 22 May 2012, accepted on 13 Jun 2012 and first published on 14 Jun 2012


Article type: Communication
DOI: 10.1039/C2CC33674J
Citation: Chem. Commun., 2012,48, 7726-7728

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    Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(III) complexes with 2,3-quinoxalinediolate ligands

    J. Vallejo, J. Cano, I. Castro, M. Julve, F. Lloret, O. Fabelo, L. Cañadillas-Delgado and E. Pardo, Chem. Commun., 2012, 48, 7726
    DOI: 10.1039/C2CC33674J

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