Issue 78, 2012
From the journal:

Chemical Communications

Synthesis of new cyclic aromatic carbene ligands bearing remote amino groups and their palladium(ii) complexes†

Shun Sugawara,a   Satoshi Kojimaa  and  Yohsuke Yamamoto*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Japan
E-mail: yyama@sci.hiroshima-u.ac.jp
Fax: +81 82-424-0723
Tel: +81 82-424-7430

Abstract

New cyclic aromatic carbene ligands bearing remote amino groups were developed. The oxidative addition of Pd(0) into the chloride precursors yielded the corresponding Pd(II) complexes whose carbene ligand was demonstrated to have stronger donor ability than classical NHCs.

Graphical abstract: Synthesis of new cyclic aromatic carbene ligands bearing remote amino groups and their palladium(ii) complexes

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Article information

DOI
https://doi.org/10.1039/C2CC33510G
Article type
Communication
Submitted
15 May 2012
Accepted
13 Aug 2012
First published
15 Aug 2012

Chem. Commun., 2012,48, 9735-9737

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Synthesis of new cyclic aromatic carbene ligands bearing remote amino groups and their palladium(II) complexes

S. Sugawara, S. Kojima and Y. Yamamoto, Chem. Commun., 2012, 48, 9735 DOI: 10.1039/C2CC33510G

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