Issue 62, 2012
From the journal:

Chemical Communications

Intramolecular carboboration of carbonylligands to form boroxycarbenes†

Celedonio M. Álvarez,a   Romen Carrillo,b   Raúl García-Rodrígueza  and  Daniel Miguel*a  

* Corresponding authors

a GIR MIOMeT-IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, C/Prado de la Magdalena s/n., Valladolid, Spain
E-mail: dmsj@qi.uva.es

b Laboratorio de Rayos X y Materiales Moleculares, Departamento de Física Fundamental II, Universidad de La Laguna, Avda. Astrofísico Francisco Sánchez s/n, Santa Cruz de Tenerife, La Laguna, Spain

Abstract

A formal direct carboboration of carbonyl ligands to form manganese boroxycarbenes in a one-pot fashion is reported.

Graphical abstract: Intramolecular carboboration of carbonyl ligands to form boroxycarbenes

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Article information

DOI
https://doi.org/10.1039/C2CC33443G
Article type
Communication
Submitted
12 May 2012
Accepted
14 Jun 2012
First published
15 Jun 2012

Chem. Commun., 2012,48, 7705-7707

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Intramolecular carboboration of carbonyl ligands to form boroxycarbenes

C. M. Álvarez, R. Carrillo, R. García-Rodríguez and D. Miguel, Chem. Commun., 2012, 48, 7705 DOI: 10.1039/C2CC33443G

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