Issue 56, 2012
From the journal:

Chemical Communications

A dramatic concentration effect on the stereoselectivity of N-glycosylation for the synthesis of 2′-deoxy-β-ribonucleosides†

Fei Yang,a   Yugen Zhua  and  Biao Yu*a  

* Corresponding authors

a State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: byu@mail.sioc.ac.cn
Fax: (0086)-21-64166128

Abstract

A dramatic concentration effect on the stereoselectivity of N-glycosylation, which is attributable to a low-concentration-facilitated remote-participation, has been disclosed, leading to convenient synthesis of the 2′-deoxy-β-ribonucleosides of biological significance.

Graphical abstract: A dramatic concentration effect on the stereoselectivity of N-glycosylation for the synthesis of 2′-deoxy-β-ribonucleosides

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Article information

DOI
https://doi.org/10.1039/C2CC33155A
Article type
Communication
Submitted
02 May 2012
Accepted
22 May 2012
First published
22 May 2012

Chem. Commun., 2012,48, 7097-7099

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A dramatic concentration effect on the stereoselectivity of N-glycosylation for the synthesis of 2′-deoxy-β-ribonucleosides

F. Yang, Y. Zhu and B. Yu, Chem. Commun., 2012, 48, 7097 DOI: 10.1039/C2CC33155A

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