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Issue 57, 2012
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Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex

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Abstract

A strictly two-coordinate nickel(II) bis(amido) complex has been prepared and its reactivity towards a variety of small molecules is described. Ni[N(SiMe3)(DIPP)]2 reacts with DMAP and acetonitrile to form T-shaped three-coordinate complexes, and preliminary results show that Ni[N(SiMe3)(DIPP)]2 is a catalyst for the hydrosilation of olefins with secondary silanes at ambient temperature.

Graphical abstract: Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex

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Supplementary files

Article information


Submitted
26 Apr 2012
Accepted
23 May 2012
First published
12 Jun 2012

Chem. Commun., 2012,48, 7146-7148
Article type
Communication

Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex

M. I. Lipschutz and T. D. Tilley, Chem. Commun., 2012, 48, 7146
DOI: 10.1039/C2CC32974C

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