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Issue 71, 2012
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A modular synthesis of dithiocarbamate pendant unnatural α-amino acids

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Abstract

Unnatural α-amino acids containing dithiocarbamate side chains were synthesized by a one-pot reaction of in situ generated dithiocarbamate anions with sulfamidates. A wide range of these anions participated in the highly regio- and stereo-selective ring opening of sulfamidates to produce the corresponding dithiocarbamate pendant α-amino acids in high yields.

Graphical abstract: A modular synthesis of dithiocarbamate pendant unnatural α-amino acids

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Supplementary files

Article information


Submitted
23 Apr 2012
Accepted
29 Jun 2012
First published
29 Jun 2012

Chem. Commun., 2012,48, 8889-8891
Article type
Communication

A modular synthesis of dithiocarbamate pendant unnatural α-amino acids

A. Saha, R. B. N. Baig, J. Leazer and R. S. Varma, Chem. Commun., 2012, 48, 8889
DOI: 10.1039/C2CC32894A

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