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Issue 67, 2012
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Stabilisation of a triply-bridging cyclopentadienyl ligand in a tetrapalladium cluster

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Abstract

An unusual triply-bridging cyclopentadienyl (C5H5 = Cp) ligand has been characterised in the tetranuclear palladium cluster [Pd3II(μ-OAc)43-Cp)Pd05-Cp)] (1). It is coordinated in the μ3122 mode to a [Pd3]4+ triangular subunit of the mixed-valence cluster 1.

Graphical abstract: Stabilisation of a triply-bridging cyclopentadienyl ligand in a tetrapalladium cluster

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Publication details

The article was received on 23 Apr 2012, accepted on 10 Jun 2012 and first published on 12 Jun 2012


Article type: Communication
DOI: 10.1039/C2CC32886K
Citation: Chem. Commun., 2012,48, 8317-8319

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    Stabilisation of a triply-bridging cyclopentadienyl ligand in a tetrapalladium cluster

    K. Yu. Monakhov, C. Gourlaouen and P. Braunstein, Chem. Commun., 2012, 48, 8317
    DOI: 10.1039/C2CC32886K

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