Issue 47, 2012
From the journal:

Chemical Communications

Half-rotation in a kinetically locked [2]catenane induced by transition metal ion substitution†

David A. Leigh,*ab   Paul J. Lusby,a   Alexandra M. Z. Slawinc  and  D. Barney Walkera  

* Corresponding authors

a School of Chemistry, University of Edinburgh, The King’s Buildings, West Mains Road, Edinburgh, UK EH9 3JJ

b School of Chemistry, University of Manchester, Oxford Road, Manchester, UK M13 9PL
E-mail: David.Leigh@manchester.ac.uk

c School of Chemistry, University of St. Andrews, Purdie Building, St. Andrews, Fife, UK KY16 9ST

Abstract

We report on a heterocircuit [2]catenane in which a reversible half-rotation of one ring about the other can be induced, and locked in place, by switching the coordination of the interlocked rings between Pd(II) and Co(III).

Graphical abstract: Half-rotation in a kinetically locked [2]catenane induced by transition metal ion substitution

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Article information

DOI
https://doi.org/10.1039/C2CC32418K
Article type
Communication
Submitted
04 Apr 2012
Accepted
21 Apr 2012
First published
24 Apr 2012

Chem. Commun., 2012,48, 5826-5828

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Half-rotation in a kinetically locked [2]catenane induced by transition metal ion substitution

D. A. Leigh, P. J. Lusby, A. M. Z. Slawin and D. B. Walker, Chem. Commun., 2012, 48, 5826 DOI: 10.1039/C2CC32418K

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