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Issue 51, 2012
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Selective one-pot synthesis of symmetrical and unsymmetrical di- and triarylamines with a ligandless copper catalytic system

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Abstract

The one-pot synthesis of symmetrical or unsymmetrical di- or triarylamines using aryl iodides or bromides and LiNH2 as ammonia source is reported. This highly selective method is based, for the first time, on a copper-catalyzed system, which does not require the presence of any additional ligand.

Graphical abstract: Selective one-pot synthesis of symmetrical and unsymmetrical di- and triarylamines with a ligandless copper catalytic system

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Article information


Submitted
28 Mar 2012
Accepted
28 Apr 2012
First published
30 Apr 2012

Chem. Commun., 2012,48, 6408-6410
Article type
Communication

Selective one-pot synthesis of symmetrical and unsymmetrical di- and triarylamines with a ligandless copper catalytic system

A. Tlili, F. Monnier and M. Taillefer, Chem. Commun., 2012, 48, 6408
DOI: 10.1039/C2CC32252H

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