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Issue 87, 2012
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Synthesis of ethers from estersvia Fe-catalyzed hydrosilylation

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Abstract

Triiron dodecacarbonyl allows for the selective reduction of esters into the corresponding ethers. This protocol has a wide substrate scope. In addition, cholesteryl pelarogonate has been reduced under the reaction conditions with an excellent yield.

Graphical abstract: Synthesis of ethers from esters via Fe-catalyzed hydrosilylation

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Article information


Submitted
23 Mar 2012
Accepted
13 Sep 2012
First published
14 Sep 2012

Chem. Commun., 2012,48, 10742-10744
Article type
Communication

Synthesis of ethers from esters via Fe-catalyzed hydrosilylation

S. Das, Y. Li, K. Junge and M. Beller, Chem. Commun., 2012, 48, 10742
DOI: 10.1039/C2CC32142D

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