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Issue 50, 2012
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Recoverable organorhodium-functionalized polyhedral oligomeric silsesquioxane: a bifunctional heterogeneous catalyst for asymmetric transfer hydrogenation of aromatic ketones in aqueous medium

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Abstract

A bifuctional heterogeneous chiral rhodium catalyst exhibited excellent catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones and their analogues in aqueous medium, which could be recovered easily and used repetitively without affecting obviously its enantioselectivity.

Graphical abstract: Recoverable organorhodium-functionalized polyhedral oligomeric silsesquioxane: a bifunctional heterogeneous catalyst for asymmetric transfer hydrogenation of aromatic ketones in aqueous medium

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Publication details

The article was received on 16 Mar 2012, accepted on 03 May 2012 and first published on 03 May 2012


Article type: Communication
DOI: 10.1039/C2CC31927F
Chem. Commun., 2012,48, 6286-6288

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    Recoverable organorhodium-functionalized polyhedral oligomeric silsesquioxane: a bifunctional heterogeneous catalyst for asymmetric transfer hydrogenation of aromatic ketones in aqueous medium

    S. Tang, R. Jin, H. Zhang, H. Yao, J. Zhuang, G. Liu and H. Li, Chem. Commun., 2012, 48, 6286
    DOI: 10.1039/C2CC31927F

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