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Issue 37, 2012
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A cascade reaction of pyrrole-2-carbaldehyde substituted Morita–Baylis–Hillman adducts in the presence of tetrabutylammonium hydroxide or acetate to construct aza-heterocycles

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Abstract

The phase-transfer catalyst promoted intramolecular transformation of pyrrole-2-carbaldehyde substituted Morita–Baylis–Hillman adducts has been disclosed, providing an efficient way to construct pyrrolo[1,2-a]azepin-7(6H)-one skeletons in moderate to good yields (up to 92%) under mild conditions.

Graphical abstract: A cascade reaction of pyrrole-2-carbaldehyde substituted Morita–Baylis–Hillman adducts in the presence of tetrabutylammonium hydroxide or acetate to construct aza-heterocycles

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Publication details

The article was received on 23 Feb 2012, accepted on 14 Mar 2012 and first published on 14 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC31358H
Citation: Chem. Commun., 2012,48, 4501-4503

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    A cascade reaction of pyrrole-2-carbaldehyde substituted Morita–Baylis–Hillman adducts in the presence of tetrabutylammonium hydroxide or acetate to construct aza-heterocycles

    L. Huang and M. Shi, Chem. Commun., 2012, 48, 4501
    DOI: 10.1039/C2CC31358H

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