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Issue 72, 2012
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Super long-term highly active and selective hydroformylation in a room temperature-solidifiable guanidinium ionic liquid with a polyether tag

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Abstract

Here we report a novel room temperature-solidifiable guanidinium methanesulfonate with a polyether tag and its use in Rh-catalysed biphasic hydroformylation of higher olefins. This novel ionic liquid can efficiently immobilize the Rh-TPPTS catalyst and render super long-term high activity and chemoselectivity, and no significant loss of activity, selectivity or Rh was observed after thirty-five cycles.

Graphical abstract: Super long-term highly active and selective hydroformylation in a room temperature-solidifiable guanidinium ionic liquid with a polyether tag

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Publication details

The article was received on 08 Feb 2012, accepted on 01 Mar 2012 and first published on 16 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC30909B
Chem. Commun., 2012,48, 9017-9019

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    Super long-term highly active and selective hydroformylation in a room temperature-solidifiable guanidinium ionic liquid with a polyether tag

    X. Jin, D. Yang, X. Xu and Z. Yang, Chem. Commun., 2012, 48, 9017
    DOI: 10.1039/C2CC30909B

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