Issue 72, 2012

Super long-term highly active and selective hydroformylation in a room temperature-solidifiable guanidinium ionic liquid with a polyether tag

Abstract

Here we report a novel room temperature-solidifiable guanidinium methanesulfonate with a polyether tag and its use in Rh-catalysed biphasic hydroformylation of higher olefins. This novel ionic liquid can efficiently immobilize the Rh-TPPTS catalyst and render super long-term high activity and chemoselectivity, and no significant loss of activity, selectivity or Rh was observed after thirty-five cycles.

Graphical abstract: Super long-term highly active and selective hydroformylation in a room temperature-solidifiable guanidinium ionic liquid with a polyether tag

Supplementary files

Article information

Article type
Communication
Submitted
08 Feb 2012
Accepted
01 Mar 2012
First published
16 Mar 2012

Chem. Commun., 2012,48, 9017-9019

Super long-term highly active and selective hydroformylation in a room temperature-solidifiable guanidinium ionic liquid with a polyether tag

X. Jin, D. Yang, X. Xu and Z. Yang, Chem. Commun., 2012, 48, 9017 DOI: 10.1039/C2CC30909B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements