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Issue 69, 2012
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Self-assembly of ordered water tetramers in an encapsulated [Br(H2O)12]− complex†

Musabbir A. Saeed,a   Avijit Pramanik,a   Bryan M. Wong,b   Syed Ataul Haque,a   Douglas R. Powell,c   Dillip Kumar Chandd  and  Md. Alamgir Hossain*a  
Author affiliations

* Corresponding authors

a Department of Chemistry and Biochemistry, Jackson State University, 1400 J. R. Lynch Street, P.O. Box 17910, Jackson, USA
E-mail: alamgir.hossain@jsums.edu
Fax: +1-601-979-3674
Tel: +1-601-979-3748

b Materials Chemistry Department, Sandia National Laboratories, Livermore, USA

c Department of Chemistry and Biochemistry, University of Oklahoma, Norman, USA

d Department of Chemistry, IIT Madras, Chennai 600036, India

Abstract

An unanticipated anion–water cluster is assembled by one bromide and three highly-ordered “water tetramers” within the cavity of a receptor, providing a perfect C3 symmetric propeller-shaped bromide–water cluster of [Br(H2O)12]−.

Graphical abstract: Self-assembly of ordered water tetramers in an encapsulated [Br(H2O)12]− complex

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Article information

https://doi.org/10.1039/C2CC30767G
Submitted
03 Feb 2012
Accepted
20 Apr 2012
First published
20 Apr 2012
Chem. Commun., 2012,48, 8631-8633
Article type
Communication
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Self-assembly of ordered water tetramers in an encapsulated [Br(H2O)12]− complex

M. A. Saeed, A. Pramanik, B. M. Wong, S. A. Haque, D. R. Powell, D. K. Chand and Md. A. Hossain, Chem. Commun., 2012, 48, 8631
DOI: 10.1039/C2CC30767G

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