Issue 31, 2012
From the journal:

Chemical Communications

Stannylplumbylenes: bonding between tetravalent tin and divalent lead†‡

Christian Drost,*a   Peter Lönneckea  and  Joachim Sielera  

* Corresponding authors

a Universität Leipzig, Institut für Anorganische Chemie, Johannisallee 29, 04103 Leipzig, Germany
E-mail: cdrost@uni-leipzig.de
Fax: +49 341 9736199
Tel: +49 341 9736130

Abstract

Depending on stoichiometry, reactions of the mixed valence Sn(0)/Sn(III) compound Sn(SnAr3)2 (1) (Ar = C6H4(OiPr)2-2,6) with the likewise substituted plumbylene PbAr2 (3) afforded either the homoleptic distannylplumbylene Pb(SnAr3)2 (4) or the heteroleptic arylstannylplumbylene Pb(Ar)SnAr3 (5), a valence isomer of a stannaplumbene.

Graphical abstract: Stannylplumbylenes: bonding between tetravalent tin and divalent lead

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Article information

DOI
https://doi.org/10.1039/C2CC30687E
Article type
Communication
Submitted
31 Jan 2012
Accepted
22 Feb 2012
First published
22 Feb 2012

Chem. Commun., 2012,48, 3778-3780

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Stannylplumbylenes: bonding between tetravalent tin and divalent lead

C. Drost, P. Lönnecke and J. Sieler, Chem. Commun., 2012, 48, 3778 DOI: 10.1039/C2CC30687E

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